- 作者: 趙敏勳 ; 鍾崇燊
- 作者服務機構: 清華大學化學系
- 中文摘要: The equilibria occurring in aqueous solutions of N,N'-bis(.beta.-carbamoylethyl)ethylenediamine, N,N'-bis(.beta.-carbamoylethyl)trimethylenediamine, N,N'-bis(.beta.-barbamoylethyl)-1,2-propylenediamine, and N,N'-bis(.beta.-carbamoylethyl)-2- hydroxytrimethylenediamine with protons and copper(II) ions as well as the deprotonation reactions of the copper(II) complexes of these four ligands have been studied by calorimetry at T=25.0.degree.C and I=0.10mol dm/sup -3/(NaClO/sub 4/). The enthalpy changes and the entropy changes for these reactions are reported and discussed.
- 英文摘要: --
- 中文關鍵字: Thermodynamics; Diamino Diamides-Copper(Ii) Complexes; Temperature; Concentration
- 英文關鍵字: 熱力學;二氨基聯氨-銅錯化合物;溫度;濃度