- 作者: 李維銘; 葉君棣
- 作者服務機構: Institute of Applied Chemistry, National Tsing Hua University, Hsinchu, Taiwan 300
- 中文摘要:
Accepting a previously proposed mechanism of ethane pyrolysis in shock tubes, experimental product distributions observed by Burcat et al have been used, through computer simulation technique, to measure rate constants of following reactions in the temperature range 1206-2386°K,
CH3+C2H6→CH4+C2H5 (2)
H+CH3→CH4 (9)
Obtained k2 values are substantially higher than the extrapolation from an Arrhenius equation reported for the same rate constant at low temperatures. Rate constant k9 is found decreasing with the system temperature at 6.3 atm of argon. - 英文摘要: --
- 中文關鍵字: --
- 英文關鍵字: --