• 作者： 鍾崇燊; 黃世琮
• 作者服務機構： Department of Chemistry, National Tsing Hua University
• 中文摘要： The possibility of a trigonal bipyramidal structure for [Cu(tet b)X]+ (blue) (where X=Cl, Br, I) is supported by the observation of two distinct d-d bands, which are assigned as dx2-y2, dxy2→dz2 and dxz, dyz→dz2 transitions respectively. the stability constants for the formation of [Cu(tet b)X]+ (blue) from [Cu(tet b)]2+ (blue) and X¯ were determined by spectrophotometric method at 25℃, 35℃ and 45℃. The corresponding ΔH° and ΔS°values were obtained from the variations of the stability constants between 25° and 45℃
• 英文摘要： --
• 中文關鍵字： --
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