• 作者： 黃繹綸，王敏靖，洪豐裕
• 作者服務機構： Department of Chemistry, National Chung Hsing University, Taichung 40227, Taiwan, R.O.C.
• 中文摘要： A cobalt-containing monodentate phosphine [(m2-PPh2CH2PPh2-k2P)Co2(CO)4][m2-h2-PhCoCP(i-Pr)2] 2f, was prepared from the reaction of (m2-PPh2CH2PPh2-k2P)Co2(CO)6 1 with PhCoCP(i-Pr)2. It was accompanied by an oxidized compound, [(m2-PPh2CH2PPh2-k2P)Co2(CO)4][m2-h2-PhCoCP(=O)(i-Pr2)] 2fo during the chromatographic process. Further reaction of 2f with Mo(CO)6 resulted in the formation of a 2f-ligated molybdenum complex 4, [(m2-PPh2CH2PPh2-k2P)Co2(CO)4][m2-h2-PhCoCP(i-Pr2)-kP]-Mo(CO)5.
• 英文摘要： --
• 中文關鍵字： Molybdenum complex; Metal-containing phosphine; Cobalt complex; DPPM.
• 英文關鍵字： --