- 作者: 蔡世華 ; 吳獻仁 ; 鍾文聖
- 作者服務機構: 交通大學應用化學系
- 中文摘要: 3,5,7-Trioxapentacyclo [ 7.2.1.0/sup 2,8/.0/sup 4,11/.0/sup 6,10/ ] dodecane, the parent compound of novel diacetal trioxacages, was synthesized from maleic anhydride cyclopentadiene adduct 1 by a four-step sequence. Attempts for the synthesis of monoaza dioxa-cage 12 failed. Ozonolysis of compound 9 in CH/sub 2/Cl/sub 2/-EtOH (1:1) at -78.degree.C followed by reduction with Me/sub 2/S gave 13 in 65% yield.
- 英文摘要: --
- 中文關鍵字: Synthesis; Trioxapentacyclo Dodecane
- 英文關鍵字: 合成