- 作者: 鄭華生; 徐健民; 施玲玲
- 作者服務機構: Institute of Chemistry, National Tsing Hua University, Hsinchu, Taiwan 300
- 中文摘要: Mossbauer parameters of frozen aqueous solutions of Sn(ClO/sub 4/)/sub 2/ in 0.5M HClO/sub 4/ did not change with the concentration of NaclO/sub 4/, so that it was used to keep the ionic strength at the desired level. When NaCl was added into Sn(ClO/sub 4/)/sub 2/ solutions, isomer shift did not change, but quadrupole splitting did. Therefore, stability constants were calculated from the quadrupole splitting data, which were in good agreement with the published values. The observed spectra could be resolved into components.
- 英文摘要: --
- 中文關鍵字: Mossbauer effect; tin-119; frozen solution; complex.
- 英文關鍵字: Mossbauer effect; tin-119; frozen solution; complex.