- 作者: 許拱北; 汪文忠
- 作者服務機構: Department of Chemistry, National Cheng Kung University, Tainan, Taiwan, R.O.C.
- 中文摘要: N, N-bis(pyrazol-1-ylmethyl)aminomethane (bpam) and N,N-bis(3, 5-dimethyl-pyrazol-1-ylmethyl)aminomethane (bdmpam) reacted with M(CO)/sub 6/ or M(CO)/sub 3/(CH/sub 3/CN)/sub 3/ in acetonitrile to give respectively fac-(bpam)M(CO)/sub 3/ and fac-(bdmpam)M(CO)/sub 3/ in good yields (M=Cr, Mo, W). These complexes are characterized by elemental analysis, IR, and NMR and compared with the related polypyrazolyborate complexes of the group VI metal carbonyls.
- 英文摘要: --
- 中文關鍵字: Synthesis; characterization; N, N-bis(pyrazol-1-ylmethyl)aminomethane and N,N-bis(3, 5-dimethyl-pyrazol-1-ylmethyl)aminomethane derivatives of the group VI metal carbonyls.
- 英文關鍵字: Synthesis; characterization; N, N-bis(pyrazol-1-ylmethyl)aminomethane and N,N-bis(3, 5-dimethyl-pyrazol-1-ylmethyl)aminomethane derivatives of the group VI metal carbonyls.