- 作者: Salah B. El-Maraghy; V. Gutmann; W. Linert
- 作者服務機構: Institute of Inorganic Chemistry, VIENNA Technological University, A-1060 Vienna, Austria
- 中文摘要: Reduction of Cd/sup 2+/ at the dropping mercury electrode in solutions of 1,3,5-trihydroxybenzene was carried out in nonbuffer solutions of 0.1M NaCIO/sub 4/. The polarogram consists of two waves, the first wave can be taken in quantitative determination of Cd/sup 2+/ in solutions containing 3.5mM 1,3,5-trihydroxybenzene in 0.1M NaCIO/sub 4/. Mn/sup 2+/ produces single well-defined diffusion controlled irreversible wave whose half-wave potential shifts to a more negative value with increasing 1,3,5-trihydroxybenzene. Me(II) forms two weak complexes, MX/sub 1/ and MX/sub 2/ at 25.degree.. The behaviour of this metal ions is summerized.
- 英文摘要: --
- 中文關鍵字: Electrochemistry; complex formation; 1,3,5-trihydroxybenzene.
- 英文關鍵字: Electrochemistry; complex formation; 1,3,5-trihydroxybenzene.