- 作者: 魏和祥; 蕭清松
- 作者服務機構: Department of Chemistry, Tamkang University, Tamsui, Taiwann 251
- 中文摘要: The spin states of iron (II) in FeL2(NCS)2 produced from the thermal decomposition of Fel3(NCS)2 (L=2-py-CR1=NR2, R1 or R2=H, Me(CH3), Ph) under nitrogen atmosphere are investigated by means of mossbauer spectroscopy and magnetic measurements. It was found that the spin states of iron (II) in substitutited bis (2-pyridylimine) iron (II) thiocyanate are included: intermediate-spin (3T1, S=1), mixed-spin of 3T2(S=2)+2T1 and spin incomplete transition of 5T2…3T1.
- 英文摘要: --
- 中文關鍵字: --
- 英文關鍵字: --