- 作者: 劉兆玄
- 作者服務機構: 國立清華大學化學系
- 中文摘要: 本文主要是根據作者近年來的研究結果,對二氟化矽—一種異常穩定的二價矽化物,其化學的近況作了綜合性的報告。基於過去被忽略的氣態反應結果,與其凍結反應結果的比較,使二氟化矽反應機構中幾個重要的混淆之處得以澄清。本文最後對二氟化矽化學與甲烯基化學的相同與相異點,提出一個較清晰的新貌。
- 英文摘要: The recent developments in the chemistry of the remarkably stable divalent silicon species, SiF , arereviewed mainly on the basis of the research of the auothor's group. Based on the results from the gas-phasereactions of difluorosilylene, which have been overlooked in the past, a number of confusing areas in thereaction mechanism of SiF are clarified. A clearer picture of the similarities and dissimilarities betweenthe chemistries of silylene and carbene is presented.
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