- 作者: Morita, Tadayoshi ; Sasaki, Kazuo ; 林稟彬 等
- 作者服務機構: Dept. of Chemistry, Faculty of Science, Tohoku Univ., Aramaki Aoba-ku, Sendai, Japan
- 中文摘要: Reaction of diethyl azulene-1,3-dicarboxylate with potassium cyanide in dimethoxyethane gave diethyl 4-cyano-, 6-cyano-, and 4,6-dicyanoazulene-1,3-dicarboxylates. This cyanation involved addition of a cyanide ion to the seven- membered ring of azulene to form a cyclopentadienide ion, followed by oxidation.
- 英文摘要: --
- 中文關鍵字: Cyanation; Electrophilic Arene; Azulene; Addition Oxidation; Potassium Cyanide
- 英文關鍵字: 氰化;親電性芳香烴;薁;加成氧化;氰化鉀