- 作者: Su-Chin Chang, Wen-Yann Yeh*, Gene-Hsiang Lee and Shie-Ming Peng
- 作者服務機構: Department of Chemistry, National Sun Yat-Sen University, Kaohsiung 804, Taiwan, R.O.C.
- 中文摘要: Reaction of Mo(CO)(h2-C2Ph2)2(h4-C4Ph4) and Me3NO in acetonitrile solvent affords Mo(NCMe)(h2-C2Ph2)2(h4-C4Ph4) 1. Compound 1 reacts with trimethylphosphine to produce Mo(PMe3)(h2-C2Ph2)2(h4-C4Ph4) 2, or reacts with diphenylacetylene to produce (h5-C5Ph5)2Mo 3 and Mo(h2-O2CPh)(h4-C4Ph4H)(h4-C4Ph4) 4. The molecular structures of 1, 2 and 4 have been determined by an X-ray diffraction study.
- 英文摘要: --
- 中文關鍵字: Molybdenum; Molybdenocene; Alkyne coupling; Cyclobutadiene complexes.
- 英文關鍵字: Molybdenum; Molybdenocene; Alkyne coupling; Cyclobutadiene complexes.