• 作者： 黃鎮台
• 作者服務機構： Department of Chemistry National Tsing Hua University; Hsinchu
• 中文摘要： 本文所討論的是靈敏度資料在化學動力學的靈敏度研究上所具有的意義與適當用法。文中特別提出了靈敏度資料對(1)闡明濃度與反應速率常數間的函數關係，以及(2)簡化反應機構的重要性。作者近期所提出的 ENSM 法，亦在此有進一步的應用與試測。
• 英文摘要： This work discusses the significance and the applications of various sensitivity information obtain-able from the modeling studies of complex reaction schemes. In particular, usage of the sensitivity coef-ficients in elucidating the functional dependence of concentration vectors upon rate coefficients is dis-cussed. This is the first time a systematic study of such an important subject has been given. We have alsoexamined the role played by the rate sensitivity coefficients in the process of simplifying complicatedmechanistic models. An exponential nonlinear sensitivity model (ENSM) proposed earlier in supplyinginformation about global parametric behavior was further tested here and the reliability of the model wasillustrated with an example.
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