- 作者: Ogilvie, J.F.
- 作者服務機構: 中央研究院原子與分子科學研究所
- 中文摘要: The coefficients c/sub j/, j.ltoreq.9, defining the potential-energy V(z) and coefficients of two other radial functions related to adiabatic and nonadiabatic effects have been determined for AlH in the electronic ground state X/sup 1/.SIGMA./sup +/ by a direct fit to the published frequencies and wavenumbers of vibration-rotational transitions of /sup 27/Al/sup 1/H and /sup 27/Al/sup 2/H. The functions are valid in the range of internuclear distance/10/sup -10/m [ 1.24, 2.60 ] . Some trends in the spectral properties of the group 13 hydrides AlH, GaH, InH and TlH are discussed. The possibility of determining the rotational magnetogyric factor g/sub J/ from the available data of only wavenumbers of vibration-rotational transitions is considered; an approximate value g/sub J/.sim.-2.25 is deduced for/sup 27/Al/sup 1/H.
- 英文摘要: --
- 中文關鍵字: Vibration-Rotational Analysis; Fundamental Radial Function; Potential Energy; Adiabatic Effect; Rotational Magnetogyric Factor; Approximate Value
- 英文關鍵字: 振動-轉動分析;基礎自由基函數;位能;絕熱效應;自旋磁化因子;逼近值