- 作者: 盧天惠 ; 陳柏翰 ; 鍾崇燊
- 作者服務機構: 清華大學物理系
- 中文摘要: The crystal structure of the title compound has been solved by X-ray diffraction..lbrak.Co(Cl)/sub 2/(N/sub 4/C/sub 18/H/sub 36/).rbrak.(ClO/sub 4/), M/sub r/=537.79, triclinic, P1, a=6.974(4), b=8.530(1), c=11.061(2).ANG., .alpha.=98.47(1),.beta.= 106.56(3), .gamma.=93.02(3).degree., V=620.8(4).ANG./sup 3/, Z=1, Dx=1.439Mg m/sup -3/,.lambda.(MoK.alpha.)=0.7093.ANG., .mu.=0.96mm/sup -1/, F(000)=291.93, T=297(3)K, R=0.072, R/sub w/=0.085 for 2121 observed reflections. The Co(III) is six- coordinate with the four N atoms of the macrocyclic ligand equatorial and two Cl ions axial, thereby resulting in a tetragonally distorted octahedral geometry. Aside from the perchlorate group, there exists a non-crystallographic inversion center at the Co(III) ion for the macrocyclic ligand and the two Cl ions which are bonded to the Co(III) ion.
- 英文摘要: --
- 中文關鍵字: X-Ray Structure; Cobalt(Iii) Complex; 14-Membered Complex; Trans-Me/Sub 8/-[14]Diene; Macrocyclic Quadridentate Ligand
- 英文關鍵字: X光結構;鈷(三價)錯合物;十四碳族錯合物;反式-八甲基十四碳二烯;巨環四牙配位基