- 作者: 嚴嘉蕙 ; 蔡世華 ; 吳獻仁
- 作者服務機構: 交通大學應用化學系
- 中文摘要: The synthesis of dioxa-cages via iodine-induced cyclization reaction can be used as a new method for the determination of the stereochemistry of the bisadducts of p-quinone with cyclopentadiene and cyclohexadiene. The bisadducts 2 and 8 were converted into the dioxa-cages 13a and 13b via a three-step sequence, respectively. The stereochemistry of 13a and 13b was determined on the basis of NOE experiments.
- 英文摘要: --
- 中文關鍵字: Dioxa Cage; Quinone; Cyclopentadiene; Cyclohexadiene; Stereochemistry
- 英文關鍵字: 二氧籠;;環戊二烯;環六二烯;立體化學