- 作者: Pingyan Bie, Chenglu Zhang , Anpai Li, Xuanjia Peng, Tongxing Wu and Xinfu Pan*
- 作者服務機構: Department of Chemistry, National Laboratory of Applied Organic Chemistry, Lanzhou University, Lanzhou 730000, P. R. China
- 中文摘要: The first total synthesis of (±)-Celaphanol A was accomplished starting from a-cyclocitral and 3,4-dimethoxy benzyl chloride in six steps. The intramolecular cyclization with BF3·Et2O and enolization in t-BuOK/t-BuOH were the key steps. The process of intramolecular cyclization afforded an all-cis isomer intermediate for synthesis of aromatic tricyclic diterpenes.
- 英文摘要: --
- 中文關鍵字: (±)-Celaphanol A; Diterpene; Total synthesis.
- 英文關鍵字: (±)-Celaphanol A; Diterpene; Total synthesis.