- 作者: Ahmad S. Shawali, Ahmad A. Abdelkhalek and Abdelwahed R. Sayed
- 中文摘要:
Department of Chemistry, Faculty of Science, University of Cairo, Giza, Egypt
In aqueous dioxane containing triethylamine the title 3-chloroformazans 1 are converted into the corresponding 1,4-bis(arylazo)-3,6-diaryl-1,2,4,5-tetrazines 3 via head-to-tail dimerization of the intitially formed 1,3-dipolar ions 2. The kinetics of triethylamine-catalyzed dehydrochlorination of 1 in 70% dioxane at 27 °C and ionic strength of 0.1 were studied. The rate data were linearly correlated with enhanced Hammett substituent constants sx- and an overall r value of 0.2 was determined for the variation of the N-aryl substituent. These results were interpreted in terms of a two-step mechanism. Also, the mechanisms of the unimolecular fragmentation of 1 and 3 in the mass spectrometer are discussed - 英文摘要: --
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