- 作者: 陳春東 ; 許憲呈 ; 李錦祥 等
- 中文摘要: A new dicopper(I) complex of 4-methyl-2,6-bis(pyrazol- 1-ylmethyl) phenolate (LOH) has been synthesized by the reaction of LOH with CuI to form LOHCu/sub 2/I/sub 2/(1), which catalyzes the oxidation of 3,5-di(t-butyl)catechol. LOHCu/sub 2/I/sub 2/ reacts with molecular oxygen to form a peroxo-dicopper(II) complex and undergoes cleavage of O-O bridge to give a new .mu./sub 4/-oxo-Cu/sup II/ tetramer with seven-membered ring coordination as characterized by X- ray crystallography.
- 英文摘要: --
- 中文關鍵字: Molecular Structure; Dicopper Complex; Seven-Membered Ring
- 英文關鍵字: 分子結構;雙銅錯合物;七員環