- 作者: Adam, F.A. ; El-Haty, M.T. ; Khalafalla, A.K. et al.
- 作者服務機構: Chemistry Dept., Aswan, Egypt
- 中文摘要: Kinetics of base hydrolysis of some new heterocyclic azomethines derived from aminotriazol and aromatic aldehydes were investigated in the presence of NaOH in 60% (wt/wt) water-ethanol medium. The base hydrolysis of these Schiff bases is strictly first-order with respect to OH/sup -/ and Schiff. The rate-determining step is suggested to be the attack of the hydroxide ion on the free base. Effect of the molecular structure of both aldehydes and amines and the nature of organic hydroxylic solvent on the hydrolysis rate was investigated and discussed.
- 英文摘要: --
- 中文關鍵字: Hydrolysis; Heterocyclic Nitrogen Compounds; Schiff Bases
- 英文關鍵字: 水解;異原子環狀氮化合物;雜環甲亞胺