- 作者: 林曦 ; 皮則可
- 作者服務機構: 台灣教育學院化學系
- 中文摘要: Five polymer-type new compounds, (.eta./sup 3/- cyclopentadienyl) palladiumchloride, (.eta./sup 3/-indenyl) palladiumchloride, (.eta./sup 3/-cycloheptatrienyl) palladiumchloride, (.eta./sup 3/-phenalenyl) palladiumchlorideand (1,2,3-.eta./sup 3/-4,5 ,6,7-.eta./sup 4/-cycloheptatrienyl) (palladium-chloride)(tricarbonyl iron) have been prepared from the reaction of Na/sub 2/PdCl/sub 4/ with 1-trimethylsilylcyclopentadiene, 1-trimethylsilylindene, 1-trimethylsilyl cycloheptatriene, 1-trimethyl- silylphenalene and 1-trimethylsilylcycloheptatriene tricarbonyl iron respectively. All the complexes are obtained in excellent yield using the improved preparation route. Furthermore, a reaction mechanism is proposed.
- 英文摘要: --
- 中文關鍵字: Preparation; Polymer-Type .Eta./Sup 3/-Allylpalladium Chlorides
- 英文關鍵字: 製備;聚合型氯化.eta./sup3/-烯丙基鈀